Electrical Terminals
How does current flow through an electrolyte?
The answer I have been given by others is that the anions and cations flow to their respective electrical terminal that is submerged in the aqueous solution. But if that is what truly happens, I would predict that the current through the solution would eventually stop once all the ions have traveled to their respective terminal. I know this does not happen, so I must have a knowledge gap in my understanding. Could someone please fill that gap for me? Thanks
The ions are replaced by ions generated from the water itself.
For instance, if you are electrolyzing CuSO4, Cu will be deposited on the cathode while H2SO4 will be generated at the anode (along with oxygen as a byproduct). H2SO4 will dissociate into H+ and SO4– ions, so the copper ions will be replaced by hydrogen ions. As the copper depletes the cathode will start to generate hydrogen gas instead.
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